By James, Dustin K., Tour, James M.
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Extra info for Molecular Wires and Electronics
1 Molecular Electronics . . . . . . . . . . . . . . . Optoelectronics . . . . . . . . . . . . . . . . . 2 Molecular Wires . . . . . . Organic Molecular Wires . . . . Oligo(2,5-thiophene ethynylene)s . Oligo(1,4-phenylene ethynylene)s . Oligo(1,4-phenylene vinylene)s . . Aromatic Ladder Oligomers . . . Oligophenylenes and Polyphenylenes Acetylene Oligomers . . . . . Carbon Nanotubes . . . . . . Organometallic Molecular Wires . . . . . .
Tour JM, Cheng L, Nackashi DP, Yao Y, Flatt AK, St Angelo SK, Mallouk TE, Franzon PD (2003) J Am Chem Soc 125:13279 56. Giacalone F, Segura JL, Martin N, Guldi DM (2004) J Am Chem Soc 126:5340 57. Zhang CY, Tour JM (1999) J Am Chem Soc 121:8783 58. Yao Y, Tour JM (1999) Macromolecules 32:2455 59. Gourdon A (1997) Synthesis of conjugated ladder oligomers. In: Joachim C, Roth S (eds) Proc NATO advanced research workshop on atomic and molecular wires, Les Houches, France, 6–10 May, 1996. Applied Science Series E, Kluwer Academic Publishers, Dordrecht 341:81 60.
9. Note that 45 is unfunctionalized, containing only a protected thiol alligator clip for later SAM formation. K. M. Tour Fig. 9 Three oligo(phenylene vinylene)s (OPVs) 45–47 synthesized in order to compare their conductance to OPEs  ring. We functionalized 46 with a nitro group on the interior aromatic core in order to determine if 46 would then act as a switch. Compound 46 is undergoing testing in a collaborator’s lab. Finally, 47 was synthesized with both a nitro functional group and protected thiol groups at both ends so that it could span two Au contacts and form a circuit via a self-assembly process.